SYHTHESIS OF TITANIUM DIOXIDE NANOPARTICLES AND ITS VARIOUS PROPERTIES

Authors:

Shaik Shaheen,Undamatla L N M Venkata Surya Prakash,Abhishek Kumar,Mohammad Arif,S.Thirumavalavan,

DOI NO:

https://doi.org/10.26782/jmcms.spl.2019.08.00091

Keywords:

Titanium dioxide nanoparticles,Spectroscopy,Crystalline,

Abstract

Sol gel technique is used in the preparation of titanium dioxide nanoparticles. 10ml of TTIP (Titanium tetra iso-propoxide) is mixed with 4.ml Isopropyl alcohol and further vaccinated at 450oC for 3 hours. Various techniques are employed to determine the crystalline phase, Fourier Transform Infrared Spectroscopy (FTIR) for the identification of functional group, Scanning Electron Micoscopy (SEM) for the partial size and surface morphology identification, Raman analysis to identify the polymorphism and local crystallinity. The other properties like optical properties of titanium dioxide nanoparticles are determined by Ultraviolet (UV) analysis. TGA (Thermo gravimetric analysis) to determine the thermal properties of titanium dioxide nanoparticles.

Refference:

I. Dalpian GM, Chelikowsky J R, Phys. Rev. “Self-Purification in
Semiconductor Nanocrystals”, Lett. 2006, 96, 226802..
II. Li G, Nogami M,“Preparation and optical properties of sol‐gel derived
ZnSe crystallites doped in glass films”,J. Appl. Phys., 1994,75,4276.
III. Quinlan FT, Kuther J, Tremel W, Knoll W, Risbud S, Stroeve P,
Reverse Micelle “Synthesis and Characterization of ZnSe
Nanoparticles”,Langmuir, 2000, 16,4049.
IV. S.Suresh, “Investigations on electrical properties of cadmium telluride
thin films by chemical bath deposition technique”,journal of Non-Oxide
Glasses. 6 (2014) 47 – 52
V. Wang WZ, Geng Y, Yan P, Liu FY, Xie Y, Qian YT, “Synthesis and
characterization of MSe (M=Zn, Cd) nanorods by a new solvothermal
method”,Inorg. Chem. Commun.1999, 2,83.
VI. Sarigiannis D, Peck JD, “Characterization of vapor-phase-grown ZnSe
nanoparticles”,Appl. Phys. Lett. 2002, 80,4024.
VII. P. Gadenne, Y. Yagil, G. Deutscher, “Transmittance and reflectance in
situ measurements of semicontinuous gold films during deposition”,J.
Appl. Phys. 66 (1989) 3019
VIII. E.H.Putley , “Materials used in Semiconductor Devices”, 2nd Ed., John
Wiley and sons Ltd. N.Y, (1967)
IX. S.S.Ballard, J.S.Browder , J.F. Ebersole , “American Institute of Physics
Handbook”, 3rd ed., D.E Gray McGraw-Hill Book Co. N.Y. (1972) p.59
X. P. K. Nair, O. Gomezdaza and M. T. S. Nair, “Metal sulphide thin film
photography with lead sulphide thin films”,Adv. Mater. Opt. Electr.,
1(1992)139

XI. H. Hirata and K. Higashiyama, “Analytical Study of the Lead Ionselective
Ceramic Membrane Electrode”,Chem. Soc. Jpn., 44(1971)
2420
XII. R. S. Kane, R. E. Cohen and R. Silbey,“Theoretical Study of the
Electronic Structure of PbS Nanoclusters”, J. Phys. Chem.,
100(1996)7928
XIII. H. Kanazawa and S. Adachi, “Optical properties of PbS”,J. Appl. Phys.,
83(1998) 5997-6001
XIV. R. K. Joshi, A. Kanjilal and H. K. Sehgal, “Solution grown PbS
nanoparticle films”,Appl. Surf. Sci., 221(2004) 43
XV. L. Shao, K.H. XChang and H.L.Hwang,“Zinc sulfide thin films deposited
by RF reactive sputtering for photovoltaic applications Appl.”, Surf.Sci.
212-213, 305-310(2003).
XVI. M.Icimura, F. Goto, Y. Ono and E.Arai, “Deposition of CdS and ZnS
from aqueous solutions by a new photochemical technique”,J. Cryst.
Growth.198-199, 308-312(1999).
XVII. R.Nomura,T. Murai, T.Toyosaki, and H.Matsuda, “Single-source
MOVPE growth of zinc sulfide thin films using zinc dithiocarbamate
complexes”,Thin Solid Films. 271 (1-2), 4-7(1995).
XVIII. P.Roy, J.R. Ota, and S.K. Srivastava, “Crystalline ZnS thin films by
chemical bath deposition method and its characterization”,Thin Solid
Films.515 (4), 1912-1917(2006).
XIX. M. S. Shinde, P. B. Ahirrao, R. S. Patil,“Structural, Optical and Electrical
Properties of NanocrystallineZnS thin films Deposited by Novel
Chemical Route”Archivesof Applied Science Research, 3 (2), 311-
317(2011)
XX. E. I. Schropp, M.Zeman, “Amorphous and Microcrystalline Silicon Solar
Cells: Modelling, Materials and Device Technology”, Kluwer Academic
Pub. Boston and London (1998)
XXI. H. Zhang, X. Ma, D. Yang, “Effects of complexing agent on CdS thin
films prepared by chemical bath deposition” Mate.Lett. 58 (2003) 5-9
XXII. K. S. Ramaiha, R. D. Pilkington, A. E. Hill, R. D. Tomlinson, A. K.
Bhatnagar, “Structural and optical investigations on CdS thin films
grown by chemical bath technique”,Mater. Chem. and Phys. 68 (2001)
22
XXIII. J. Lee, “Comparison of CdS films deposited by different techniques”,
Effects on CdTe solar cellAppl. Sur. Sci. 252 (2005) 1398

View | Download